A new rearranged tricyclic abietane diterpenoid from Salvia chloroleuca Rech. f. & Allen

Nat Prod Res. 2016;30(1):120-4. doi: 10.1080/14786419.2015.1038536. Epub 2015 May 15.

Abstract

Phytochemical investigation of the roots of Salvia chloroleuca led to the isolation and identification of a new rearranged abietane diterpenoid (1). Its structure was elucidated by interpretation of the 1D and 2D NMR spectra and completed by the analysis of the HR-ESI-MS data. Compound 1 is the secondly reported compound on a rearranged tricyclic abietane (4,5-seco-5,10-friedo-abietane) diterpenoid with a ketal functionality between C-2 and C-11. A plausible biosynthetic pathway of 1 was also proposed.

Keywords: Lamiaceae; Salvia chloroleuca; rearranged diterpenoid.

MeSH terms

  • Abietanes / chemistry
  • Abietanes / isolation & purification
  • Acetone
  • Fabaceae
  • Magnetic Resonance Spectroscopy
  • Molecular Structure
  • Plant Extracts / chemistry
  • Plant Roots / chemistry
  • Salvia / chemistry
  • Salvia / metabolism
  • Solvents
  • Spectrometry, Mass, Electrospray Ionization

Substances

  • Abietanes
  • Plant Extracts
  • Solvents
  • Acetone